Selective Synthesis of Benzaldehydes by Hypochlorite Oxidation of Benzyl Alcohols under Phase Transfer Catalysis

Bijudas, K. and Bashpa, P. and Bibin, V.P. and Nair, Laksmi and Priya, A.P. and Aswathy, M. and Krishnendu, C. and Lisha, P. (2015) Selective Synthesis of Benzaldehydes by Hypochlorite Oxidation of Benzyl Alcohols under Phase Transfer Catalysis. Bulletin of Chemical Reaction Engineering & Catalysis , 10 (1). pp. 38-42. ISSN 1978-2993

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Official URL: http://dx.doi.org/10.9767/bcrec.10.1.7189.38-42

Abstract

The selective synthesis of benazaldehyde and substituted benzaldehydes from corresponding benzyl al-cohols has been carried out by using hypochlorite as an oxidant in organic medium under phase trans-fer catalysis. The reaction is highly selective since no traces of benzoic acid or substituted benzoic acids have been detected and the yield is found to be more than 90%. The products obtained were precipi-tated as 2,4-dinitrophenylhydrazone and the recrystallised products were characterized by melting point and by spectrophotometric techniques like infra red and UV-Visible analysis. © 2015 BCREC UNDIP. All rights reserved.

Item Type:Article
Uncontrolled Keywords:Selective synthesis; Hypochlorite; Benzyl alcohol; Substituted benzyl alcohols; Phase transfer catalysis
Subjects:T Technology > TP Chemical technology
Q Science > QD Chemistry
Divisions:UNDIP Journal > Bulletin of Chemical Reaction Engineering and Catalysis
ID Code:45199
Deposited By:Dr. Istadi Istadi
Deposited On:03 Mar 2015 13:36
Last Modified:03 Mar 2015 13:36

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