Bijudas, K. and Bashpa, P. and Bibin, V.P. and Nair, Laksmi and Priya, A.P. and Aswathy, M. and Krishnendu, C. and Lisha, P. (2015) Selective Synthesis of Benzaldehydes by Hypochlorite Oxidation of Benzyl Alcohols under Phase Transfer Catalysis. Bulletin of Chemical Reaction Engineering & Catalysis , 10 (1). pp. 38-42. ISSN 1978-2993
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Official URL: http://dx.doi.org/10.9767/bcrec.10.1.7189.38-42
Abstract
The selective synthesis of benazaldehyde and substituted benzaldehydes from corresponding benzyl al-cohols has been carried out by using hypochlorite as an oxidant in organic medium under phase trans-fer catalysis. The reaction is highly selective since no traces of benzoic acid or substituted benzoic acids have been detected and the yield is found to be more than 90%. The products obtained were precipi-tated as 2,4-dinitrophenylhydrazone and the recrystallised products were characterized by melting point and by spectrophotometric techniques like infra red and UV-Visible analysis. © 2015 BCREC UNDIP. All rights reserved.
Item Type: | Article |
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Uncontrolled Keywords: | Selective synthesis; Hypochlorite; Benzyl alcohol; Substituted benzyl alcohols; Phase transfer catalysis |
Subjects: | T Technology > TP Chemical technology Q Science > QD Chemistry |
Divisions: | UNDIP Journal > Bulletin of Chemical Reaction Engineering and Catalysis |
ID Code: | 45199 |
Deposited By: | Dr. Istadi Istadi |
Deposited On: | 03 Mar 2015 13:36 |
Last Modified: | 03 Mar 2015 13:36 |
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