Methane-Carbon Dioxide: Conversions to Syngas and Hydrocarbons

Abstract

This monograph describes the new innovation that has recently been developed for the CH4-€“CO2 conversions process. Optimization of CO2 reforming of methane to synthesis gas with the help of experimental design, empirical modeling and ANN modeling are developed for CORM in presence of oxygen. An overview on dynamic equilibrium analysis has shown that an increase of sweep factors induced more significant enhancement hydrogen permeation than permselective area. The NiO/CeO2 catalyst showed potential as catalyst for the CORM. The application of a hybrid catalytic DBD plasma reactor has the potential for the co-generation of C2+ hydrocarbons and synthesis gases from methane and carbon dioxide. Carbon dioxide as co-feed has important effects on the carbon suppression. It can be concluded that three factors, i.e. CH4/CO2 feed ratio, total feed flow rate, and discharge voltage, in the DBD plasma reactor system have significant effects on the reactor performance. The hybrid catalytic DBD plasma reactor is more suitable for CO2 OCM process than the conventional catalytic reactor over CaO-MnO/CeO2 catalyst. Further innovation and improvement of current research on CH4 and CO2 are required to increase conversion and selectivity and to commercialize the process.